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    金沙国家大气本底站甲烷浓度变化特征及影响分析

    Study on the concentration variation and impact factors of CH4 in Jinsha atmospheric background station

    • 摘要: 基于2007—2021年CH4浓度和气象数据对华中区域大气本底站金沙站CH4浓度变化特征及影响因素进行分析。结果表明:金沙站CH4浓度在2010年以后上升明显,呈显著增长趋势,增长速率高于瓦里关站,且月变化幅度大;2020年和2021年CH4原始浓度分别为2093.9×10-9和2096.6×10-9,本底浓度分别为2068.7×10-9和2083.0×10-9,筛分后的夏秋季本底数据与原始数据比值较冬春季更低,区域输送对本底浓度影响大。江汉湖群CH4排放夏秋季达到最大,受传输滞后和化学反应影响,金沙站CH4浓度秋季>冬季>夏季>春季,其中高值出现在9月和10月。CH4日变化呈现双峰型特征,08:00—10:00和18:00—20:00浓度最高;CH4 浓度受到温度和湿度等气象因素的影响,CH4浓度高值出现在气温20~25 ℃、偏西偏北风方向,随风速增加和湿度下降浓度呈下降趋势。金沙站受短路径传输影响明显,春季和冬季来自陕西和河南的北向短距离气团占比最大,且该路径下CH4浓度最高,而夏季来自江西的短路径浓度最高,秋季以省内短路径占比最高。

       

      Abstract: Based on the observation data of CH4 concentrations and meteorological parameters from 2007 to 2021 in Jinsha station,an atmospheric background station in central China,were used to investigate the variations of CH4 concentrations and the influencing factors.CH4 concentrations in Jinsha station increased significantly after 2010 with a higher increasing trend and larger monthly fluctuations than that in Waliguan station.The original concentrations of CH4 were 2093.9×10-9 and 2096.6×10-9,and the background concentrations were 2068.7×10-9 and 2083.0×10-9 in 2020 and 2021,respectively.After REBS (robust extraction of baseline signal) filtering,the ratios between original and background concentrations in summer were lower than those in winter and spring,revealing the significant impact of regional transport on CH4 background concentrations in Jinsha.The emission of CH4 in the lake agglomeration of Jianghan Plain peaked in summer and autumn.Under the influence of transport delay and chemical reaction,CH4 concentrations in Jinsha ranked in the order of autumn>winter>summer>spring,with the highest values in September and October.The diurnal variation of CH4 was in bimodal distribution and the highest values occurred at 08:00-09:00 and 18:00-20:00.Influenced by meteorological factors such as temperature and humidity,CH4 concentrations peaked at the temperature of 20-25 ℃ and in the wind direction of westerly and northerly,decreasing with enhancing wind speed and descending humidity.CH4 concentrations in Jinsha station were affected by short-distance transport.The northern air mass from Shaanxi and Henan provinces has the greatest contribution in spring and winter,leading to the highest CH4 concentrations in Jinsha,while the air mass from Jiangxi province accounted for the highest proportion in summer and the inner-province short-distance transport was predominant in autumn.

       

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