Using conventional meteorological data, air pollutant concentration monitoring data, and meteorological reanalysis data (The European Centre for Medium-Range Weather Forecasts, ECMWF, and National Centers for Environmental Prediction, NCEP) in Harbin from 2014 to 2017, we compared the evolution and diurnal variation of five criteria air pollutants (PM2.5, PM10, CO, SO2, and NO2) before and after the winter heating period from 2014 to 2017, and analyzed the causes of air pollution in combination with meteorological data.The results indicated that during the heating period, the concentration of five criteria air pollutants increase significantly and remain at a relatively high level.The daily mean SO2 concentration is mostly affected by heating among all the five air pollutants.Concentrations of PM2.5, PM10, CO, and NO2 all have peak values or larger values in early November.PM2.5 and PM10 vary consistently with each other, exhibiting high homology.In terms of diurnal variation, PM2.5, PM10, NO2, SO2, and CO all exhibit bimodal distributions, but their variations are not completely consistent.Air pollutants released by coal burning during the heating period and the meteorological conditions that are not conducive to pollutants' diffusion lead to the aggravation of air pollution in Harbin.During the overlapping period of straw burning and heating emissions, straw burning seriously affects air quality, which can contribute to 69.4% of PM2.5 concentration.